Seasonality of the Transpiration Fraction and Its Controls Across Typical Ecosystems Within the Heihe River Basin

Understanding the seasonality of the transpiration fraction (T/ET) of total terrestrial evapotranspiration (ET) is vital for coupling ecological and hydrological systems and quantifying the heterogeneity among various ecosystems. In this study, a two‐source model was used to estimate T/ET in five ecosystems over the Heihe River Basin. In situ measurements of daily energy flux, sap flow, and surface soil temperature were compared with model outputs for 2014 and 2015. Agreement between model predictions and observations demonstrates good performance in capturing the ecosystem seasonality of T/ET. In addition, sensitivity analysis indicated that the model is insensitive to errors in measured input variables and parameters. T/ET among the five sites showed only slight interannual fluctuations while exhibited significant seasonality. All the ecosystems presented a single‐peak trend, reaching the maximum value in July and fluctuating day to day. During the growing season, average T/ET was the highest for the cropland ecosystem (0.80 ± 0.13), followed by the alpine meadow ecosystem (0.79 ± 0.12), the desert riparian forest Populus euphratica (0.67 ± 0.07), the Tamarix ramosissima Ledeb desert riparian shrub ecosystem (0.67 ± 0.06), and the alpine swamp meadow (0.55 ± 0.23). Leaf area index exerted a first‐order control on T/ET and showed divergence among the five ecosystems because of different vegetation dynamics and environmental conditions (e.g., water availability or vapor pressure deficits). This study quantified transpiration fraction across diverse ecosystems within the same water basin and emphasized the biotic controls on the seasonality of the transpiration fraction

On the long-time asymptotics of the modified Camassa-Holm equation with step-like initial data

We study the long time asymptotic behavior for the Cauchy problem of the modified Camassa-Holm (mCH) equation with step-like initial data \begin{align} &m_{t}+\left(m\left(u^{2}-u_{x}^{2}\right)\right)_{x}=0, \quad m=u-u_{xx}, \nonumber \\ &u(x,0)=u_0(x)\to \left\{ \begin{array}{ll} A_1, &\ x\to+\infty,\\[5pt] A_2, &\ x\to-\infty, \end{array}\right.\nonumber \end{align} where $A_1$ and $A_2$ are two positive constants. Our main technical tool is the representation of the Cauchy problem with an associated matrix Riemann-Hilbert (RH) problem and the consequent asymptotic analysis of this RH problem. Based on the spectral analysis of the Lax pair associated with the mCH equation and scattering matrix, the solution of the step-like initial problem is characterized via the solution of a RH problem in the new scale $(y,t)$. We adopt double coordinates $(\xi, c)$ to divide the half-plane $\{ (\xi,c): \xi \in \mathbb{R}, \ c> 0, \ \xi=y/t\}$into four asymptotic regions. Further using the Deift-Zhou steepest descent method, we derive different long time asymptotic expansion of the solution$u(y,t)$in different space-time regions by the different choice of g-function. The corresponding leading asymptotic approximations are given with the slow/fast decay step-like background wave in genus-0 regions and elliptic waves in genus-2 regions. The second term of the asymptotics is characterized by Airy function or parabolic cylinder model. Their residual error order is$\mathcal{O}(t^{-1})$or$\mathcal{O}(t^{-2})$ respectively.Comment: 86 page

Functionalization of TiO₂ for Better Performance as Orthopedic Implants

This review mainly focuses on the surface functionalization approaches of titanium dioxide (TiO2) to prevent bacterial infections and facilitate osteointegration simultaneously for titanium (Ti)-based orthopedic implants. Infection is one of the major causes of implant failure. Meanwhile, it is also critical for the bone-forming cells to integrate with the implant surface. TiO2 is the native oxide layer of Ti which has good biocompatibility as well as enriched physical, chemical, electronic, and photocatalytic properties. The formed nanostructures during fabrication and the enriched properties of TiO2 have enabled various functionalization methods to combat the micro-organisms and enhance the osteogenesis of Ti implants. This review encompasses the various modifications of TiO2 in aspects of topology, drug loading, and element incorporation, as well as the most recently developed electron transfer and electrical tuning approaches. Taken together, these approaches can endow Ti implants with better bactericidal and osteogenic abilities via the functionalization of TiO2

plant functional traits and relative aboveground biomass

This sheet contains traits and relative aboveground biomass of each species in three grasslands over two years

Data from: Temporal intraspecific trait variability drives responses of functional diversity to inter-annual aridity variation in grasslands

Inter-annual climate variation alters functional diversity through intraspecific trait variability and species turnover. We examined these diversity elements in three types of grasslands in Northern China, including two temperate steppes and an alpine meadow. We evaluated the differences in community-weighted means (CWM) of plant traits and functional dispersion (FDis) between two years with contrasting aridity in the growing season. Four traits were measured: specific leaf area (SLA), leaf dry matter content (LDMC), leaf nitrogen concentration (LNC) and the maximum plant height (H). CWM for SLA of the alpine meadow increased in the dry year while that of the temperate steppe in Qinghai showed opposing trends. CWM of LDMC in two temperate steppes became higher and CWM of LNC in all grasslands became lower in the dry year. Compared with the wet year, FDis of LDMC in the alpine meadow and FDis of LNC in the temperate steppe in Qinghai decreased in the dry year. FDis of H was higher in the dry year for two temperate steppes. Only in the temperate steppe in Qinghai did the multi-FDis of all traits experience a significant increase in the dry year. Most of the changes in CWM and FDis between two years were explained by intraspecific trait variation rather than shifts in species composition. This study highlights that temporal intraspecific trait variation contributes to functional responses to environmental changes. Our results also suggest it would be necessary to consider habitat types when modelling ecosystem responses to climate changes, as different grasslands showed different response patterns

Hyperbranched Poly(aroxycarbonyltriazole)s: Metal-Free Click Polymerization, Light Refraction, Aggregation-Induced Emission, Explosive Detection, and Fluorescent Patterning

The metal-free click polymerization (MFCP) of azide and alkyne has become a powerful tool for the synthesis of functional polytriazoles. Among which, the MFCP of propiolate and azide has been used to prepare functional linear poly(aroxycarbonyltriazole)s (PACTs). Their hyperbranched analogues, however, have been rarely prepared In this paper, hyperbranched PACTs with satisfactory molecular weights and high regioregularities were synthesized in high yields by the MFCP of tripropiolates (1) and tetraphenylethene (TPE)-containing diazide (2) under the optimized reaction conditions without protection from oxygen and moisture. The resultant polymers are soluble in common organic solvents and thermally stable, with 5% loss of their weights at temperatures higher than 330 degrees C. The polymers exhibit high refractive indices with low chromatic dispersion. Thanks to their contained TPE units, the polymers show the unique feature of aggregation induced emission, and their aggregates can function as fluorescent sensors for the detection of explosives with the superamplification quenching effect Furthermore, the polymers can be readily photo-cross-linked, yielding two-dimensional fluorescent patterns with high resolution

Temporal intraspecific trait variability drives responses of functional diversity to interannual aridity variation in grasslands

Abstract Interannual climate variation alters functional diversity through intraspecific trait variability and species turnover. We examined these diversity elements in three types of grasslands in northern China, including two temperate steppes and an alpine meadow. We evaluated the differences in community‐weighted means (CWM) of plant traits and functional dispersion (FDis) between 2 years with contrasting aridity in the growing season. Four traits were measured: specific leaf area (SLA), leaf dry matter content (LDMC), leaf nitrogen concentration (LNC), and the maximum plant height (H). CWM for SLA of the alpine meadow increased in the dry year while that of the temperate steppe in Qinghai showed opposing trends. CWM of LDMC in two temperate steppes became higher and CWM of LNC in all grasslands became lower in the dry year. Compared with the wet year, FDis of LDMC in the alpine meadow and FDis of LNC in the temperate steppe in Qinghai decreased in the dry year. FDis of H was higher in the dry year for two temperate steppes. Only in the temperate steppe in Qinghai did the multi‐FDis of all traits experience a significant increase in the dry year. Most of the changes in CWM and FDis between 2 years were explained by intraspecific trait variation rather than shifts in species composition. This study highlights that temporal intraspecific trait variation contributes to functional responses to environmental changes. Our results also suggest it would be necessary to consider habitat types when modeling ecosystem responses to climate changes, as different grasslands showed different response patterns

A recyclable and reusable supported Cu(I) catalyzed azide-alkyne click polymerization

The azide-alkyne click polymerization (AACP) has emerged as a powerful tool for the synthesis of functional polytriazoles. While, for the Cu(I)-catalyzed AACP, the removal of the catalytic Cu(I) species from the resulting polytriazoles is difficult, and the research on the recyclability and reusability of the catalyst remains intact. Herein, we reported the first example of using recyclable and reusable supported Cu(I) catalyst of CuI@A-21 for the AACP. CuI@A-21 could not only efficiently catalyze the AACP but also be reused for at least 4 cycles. Moreover, pronounced reduction of copper residues in the products was achieved. Apart from being a green and cost-effective polymer synthesis strategy, this method will also broaden the application of AACP in material and biological sciences and provide guidelines for other polymerizations with metal catalysts